You may also get penitus oculatus armor in Dragon Bridge, to the southwest of Solitude, in the penitus oculatus outpost. You have to kill the penitus oculatus agent to get it though, unless you have maxed out your pickpocketing skill and bought the appropriate perks.
I think the only way to get Gen. Tullius's armor is to join the Stormcloak rebellion, and kill him at the end of that quest-line.