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you need to go without feeding for at least 1 day to get the power Vampire Seduction....you can use the bite power on them (feed while standing)...or finishing move (if you done a finishing move as a vampire lord yet)
If you are talking about the vampire lord power bite, you need to be killing a human npc (bandits, forsworn, civilians) when they get low on health power attack and it will make you chomp their necks.