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It has a very rare chance to randomly spawn in chests. But I personally find it easier just to make it, to make it you'll need 90 Smithing and the perk "Daedric Smithing". But to answer your question, Yes you can eventually find it through chests scattered across Skyrim.
The Breton class, is pretty good with magic but can be used for a Mage-Warrior type class if you're looking for that kind of build. If my suggestion didn't help I'm sorry. Good luck with your character class!
Both look great on Male and Female characters honestly (my opinion) but I like Dragonscale more than Dragonplate. I just think Dragonplate looks a little bland... of course this is just my opinion, feel free to choose!